赵玉宝，于2012年在中国科学院化学研究所获得博士学位。获国家自然科学基金面上项目，广州市“羊城学者”科研项目，广东省科技厅基础与应用基础研究基金面上项目等资助，主要开展水污染控制原理与技术方面的应用基础研究工作，在类芬顿反应过程金属单原子催化材料载体效应调控和光催化界面局域极性中心调控方面做出创新性的研究工作，代表性成果发表于Nature Communications, Angewandte Chemie International Edition, ACS Catalysis，Applied Catalysis B: Environmental等杂志。担任ACS ES&T Engineering，Chinese Chemical Letters，Global Environment Science等国际期刊青年编委。
教育背景
博士学位，2009.09-2012.06中国科学院化学研究所
硕士学位，2006.09-2009.06中国科学院山西煤炭化学研究所
学士学位，2002.09-2006.06内蒙古大学化学化工学院
工作经历
广州大学大湾区环境研究院（2019.06-2024.03）
韩国浦项工科大学环境工程系（2018.08-2019.05）
德国马克斯-普朗克胶体与界面研究所(2016.02-2018.05)
美国德克萨斯大学奥斯汀分校机械工程系(2014.02-2016.01)
新加坡国立大学化学系(2012.09-2014.01)
研究方向:
1.单原子催化高级氧化水处理技术；催化材料微结构调控与反应机制研究
2.聚合有机光催化材料设计；光催化制过氧化氢；光化学/光物理机制分析。
学术任职：
ACS ES&T Engineering，Chinese Chemical Letters，Global Environment Science等国际期刊青年编委
科研项目：
1.国家自然科学基金 面上项目 （21976041），主持，结题。
高载量金属单原子催化单过硫酸盐去除水体难降解有机污染物，2019.01−2023.12。
2.广州市教育局“羊城学者”科研项目 （202235238），主持，在研
分子氧界面活化机制调控在水消毒中的应用基础研究，2023.04−2025.03。
3.广东省科技厅基础与应用基础研究基金 面上项目 （2023A1515010788），主持，在研
光驱动聚合七嗪亚胺框架上过氧化氢生成效率关键决定机制研究，2023.01−2025.12。
4.广州市科技局市校（院）联合资助基础研究项目 （202201020168），主持，结题。
基于分子氧选择性还原与生物质衍生物增值的太阳能转化存储体系与机制，2022.04−2024.03。
代表性论文:
1.Zhao, Y.*; Zhang, P.; Yang, Z.; Li, L.; Gao, J.; Chen, S.; Xie, T.; Diao, C.; Xi, S.; Xiao, B.; Hu, C.; Choi, W.*,Mechanistic analysis of multiple processes controlling solar-driven H2O2synthesis using engineered polymeric carbon nitride.Nat. Commun.2021,12, 3701. (ESI-Top 1% highly cited paper)
2.Zhao, Y.; Ma, W.; Li, Y.; Ji, H.; Chen, C.; Zhu, H.; Zhao, J.*, The surface-structure sensitivity of dioxygen activation in the anatase-photocatalyzed oxidation reaction.Angew. Chem. Int. Ed.2012,51, (13), 3188-3192.
3.Zhao, Y.*; Antonietti, M.Visible‐light‐irradiated graphitic carbon nitride photocatalyzed Diels–Alder reactions with dioxygen as sustainable mediator for photoinduced electrons.Angew. Chem. Int. Ed.2017,56, 9336.
4.Zhao, Y.*; Gao, J.; Yang, Z.; Li, L.; Cui, J.; Zhang, P.*; Hu, C.*; Diao, C.; Choi, W.*, Efficient exciton dissociation in ionically interacted methyl viologen and polymeric carbon nitride for superior H2O2photoproduction.ACS Catal.2023,13, 2790-2801.
5.Cui, J.; Li, L.; Shao, S.; Gao, J.; Wang, K.; Yang, Z.; Zeng, S.; Diao, C.;Zhao, Y.*; Hu, C., Regulating the metal–support interaction: Double jump to reach the efficiency apex of the Fe–N4-catalyzed Fenton-like reaction.ACS Catal.2022,12, 14954-14963.
6.Cui, J.; Li, L.; Wu, Y.; Gao, J.; Wang, K.; Diao, C.; Hu, C.;Zhao, Y.*, Robust Fe-N4 center with optimized metal-support interaction for efficient pollutant degradation by Fenton-like reaction.Appl. Catal. B.2023,331, 122706.
近三年研究论文:
2023年
1.Zhao, Y.*; Gao, J.; Yang, Z.; Li, L.; Cui, J.; Zhang, P.*; Hu, C.*; Diao, C.; Choi, W.*, Efficient exciton dissociation in ionically interacted methyl viologen and polymeric carbon nitride for superior H2O2photoproduction.ACS Catal.2023,13, 2790-2801.
2.Cui, J.; Li, L.; Wu, Y.; Gao, J.; Wang, K.; Diao, C.; Hu, C.;Zhao, Y.*, Robust Fe-N4 center with optimized metal-support interaction for efficient pollutant degradation by Fenton-like reaction.Appl. Catal. B.2023,331, 122706.
3.Shao, S.; Cui, J.; Wang, K.; Yang, Z.; Li, L.; Zeng, S.; Cui, J.; Hu, C.;Zhao, Y.*, Efficient and durable single-atom Fe catalyst for Fenton-like reaction via mediated electron-transfer mechanism.ACS EST Engg.2023,3, 36-44.
4.Yang, Z.; Li, L.; Zeng, S.; Cui, J.; Wang, K.; Hu, C.;Zhao, Y.*, Nanoarchitecture manipulation by polycondensation on KCl crystals toward crystalline lamellar carbon nitride for efficient H2O2photoproduction.ACS Appl. Mater. Interfaces.2023,15, 8232-8240.
5.Zeng, S.; Li, L.; Yang, Z.; Cui, J.; Wang, K.; Hu, C.;Zhao, Y.*, Artificial photosynthesis of H2O2by synergistically interplayed ZnIn2S4and K+-incorporated polymeric carbon nitride.ACS Sustainable Chem. Eng.2023, 11, 7094-7101.
6.Yang, Z.; Guo, B.; Hu, Z.; Cui, J.; Cui, J.; Li, L.; Hu, C.;Zhao, Y.*, Highly efficient removal of Cs+from water by an ionic lamellar carbon nitride framework.J. Mater. Chem. A.2023, 11,11859-11865.
7.Yang, Z.; Guo, B.; Hu, Z.; Wang, K.; Cui, J.; Li, L.; Hu, C.;Zhao, Y.*, Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H2O2photo-production.Chin. Chem. Lett.2023, 109251.
8.Wang, K.; Cui, J.; Li, L.; Yang, Z.; Zeng, S.; Hu, Z.; Hu, C.;Zhao, Y.*, Single-atom sites in metal–N4configuration for efficient abatement of refractory organic pollutants via Fenton-like reaction.Chem. Eng. J.2023, 146622.
2022年
1.Zeng, S.; Li, L.; Yang, Z.; Cui, J.; Shao, S.; Wang, K.; Cui, J.;Zhao, Y.*, Polymeric carbon nitride from inorganic precursor in eutectic salts: Enhanced exciton dissociation and photocatalytic H2O2production.J. Phys. Chem. C.2022,126, 20028-20035.
2.Yang, Z.; Li, L.; Gao, J.; Zeng, S.; Cui, J.; Shao, S.; Wang, K.; Ma, D.; Hu, C.;Zhao, Y.*, Optimizing the band structure of crystalline potassium poly(heptazine imide) for enhanced photocatalytic H2O2production and pollutant degradation.ACS EST Engg.2022,2, 2142-2149.
3.Yang, Z.; Li, L.; Cui, J.; Shao, S.; Zeng, S.; Wang, K.; Ma, D.; Hu, C.;Zhao, Y.*, Nanoarchitectonics in the ionothermal synthesis for nucleation of crystalline potassium poly(heptazine imide) towards an enhanced solar-driven H2O2production.Chem. Eur. J.2022,28, e202202122.
4.Shao, S.; Cui, J.; Li, L.; Wang, M.; Zhang, P.; Cui, J.; Hu, C.;Zhao, Y.*, Rapid pollutant degradation by peroxymonosulfate via an unusual mediated-electron transfer pathway under spatial-confinement.RSC Adv.2022,12, 5236-5244.
5.Cui, J.; Shao, S.; Li, L.; Zhang, P.; Cui, J.; Hu, C.;Zhao, Y.*, Nanoconfinement-regulated peroxymonosulfate activation via an anomalously efficient mediated electron-transfer pathway on cobalt.ACS EST Engg.2022,2, 2014-2022.
6.Cui, J.; Shao, S.; Gao, J.; Yang, Z.; Li, L.; Zeng, S.; Wang, K.; Cui, J.;Zhao, Y.*; Hu, C., Efficient Single-Atom Fe-Catalyzed Fenton-like Reaction Involving Peroxymonosulfate for BPA Degradation by High-Valent Fe(IV)=O.ACS EST Water.2022,2, 2698-2705.
7.Cui, J.; Li, L.; Shao, S.; Gao, J.; Wang, K.; Yang, Z.; Zeng, S.; Diao, C.;Zhao, Y.*; Hu, C., Regulating the metal–support interaction: Double jump to reach the efficiency apex of the Fe–N4-catalyzed Fenton-like reaction.ACS Catal.2022,12, 14954-14963.
2021年
1.Zhao, Y.*; Zhang, P.; Yang, Z.; Li, L.; Gao, J.; Chen, S.; Xie, T.; Diao, C.; Xi, S.; Xiao, B.; Hu, C.; Choi, W.*,Mechanistic analysis of multiple processes controlling solar-driven H2O2synthesis using engineered polymeric carbon nitride.Nat. Commun.2021,12, 3701. (ESI highly cited paper)
